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Chemists use colour to detect forever chemicals

Chloe Taylor pollution testing

Chemists at the University of Tasmania have developed an instant colour-change test for so-called forever chemicals, or PFAS, in contaminated soil or water.

The proof-of-concept study for one of the most prevalent perfluorinated alkyl substances (PFAS), known as PFOA, has been published in the journal Chemical Communications.

The test relies on a brightly coloured molecule prepared by alumna and PhD candidate Chloe Taylor (BMarAntSc 2017, BSc Hons 2018). The molecule was designed with a cavity that is filled by the pollutant and changes colour if PFAS is present.

“My initial interest was in making new molecules to see what they could do. It is very exciting to take what I’ve made and apply it to a real-world problem,” said Ms Taylor.

“We developed a solution that is red when it’s on its own, but when it comes into contact with the pollutant it changes to green. The molecule acts like a basket or net and when it catches one of the single pollutants, this causes a physical change that results in the colour change.”

Project leader Dr Nathan Kilah said it was the first instant colour-change test developed for such chemicals.

PFAS were widely used in the manufacturing process for a range of products including stain-resistant fabrics, beauty products, fast food packaging and non-stick cookware.

These chemicals were also used extensively in water-based firefighting foams, which means they exist in high concentrations around airfields throughout Australia and the world.

Dr Kilah said the presence of PFAS could potentially impact the communities surrounding the contamination sites, so it was important to have access to a fast and accurate method of detection.

“One of the great challenges of this type of pollution is to determine where it is found in the environment. This normally requires expensive, specialised lab equipment that is a long way away from the contaminated site,” he said.

“This test represents a rapid way of determining if the common PFAS pollutant perfluorooctanoic acid is present in soil samples.

“The end goal is to empower everyday people to assess whether their soil or water is contaminated with these pollutants.

“We want to make this method as easy as shaking some soil with a mix of our sensor, or perhaps translate it to a dipstick. We’ve got a way to go to bring a product to the market, but the science of our molecule and the need for such a product are very clear.”

The team is working on commercialising their discovery with the University to make it available not only to environmental scientists, but also to people at home who are concerned about their own potential PFAS exposure.

ChemComm is the Royal Society of Chemistry’s journal for urgent communications of outstanding significance from across the chemical sciences.

This article featured in the monthly eNews Alumni and Friends. If you are a member of the University of Tasmania community and would like to receive this publication, please provide or update your email address.

Published on: 10 Nov 2021 12:49pm